Answer for Painting vinyl window casing?

Depends on the vinyl, some is designed to be painted. The shiny and very slick vinyl isn't paintable. What you can do is try XIM 400 or Plastic & Vinyl NT Bonding Primer. XIM makes the best primers and should have one that will stick.

Priming and painting plastics, including vinyl, will involve some prep; very clean surface that is also sanded to remove the sheen and provide a rough surface for the primer to bond to.

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